Isolation and characterization of bis(silylene)-stabilized antimony(I) and bismuth(I) cations.

ABSTRACT: Monovalent group 15 cations L₂Pn + (L = σ-donor ligands, Pn = N, P, As, Sb, Bi) have attracted significant experimental and theoretical interest because of their unusual electronic structures and growing synthetic potential. Herein, we describe the synthesis of a family of antimony(I) and bismuth(I) cations supported by a bis(silylene) ligand [(TBDSi₂)Pn][BAr^F₄] (TBD = 1, 8, 10, 9-triazaboradecalin; Ar^F = 3,5-CF₃-C₆H₃; Pn = Sb, (2); Bi, (3)). The structures of 2 and 3 have been unambiguously characterized spectroscopically and by X-ray diffraction analysis and DFT calculations. They feature bis-coordinated Sb and Bi atoms which exhibit two lone pairs of electrons. The reactions of 2 and 3 with methyl tr

SUBMITTER: Wang X 

PROVIDER: S-EPMC10206093 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature