Solid-state synthesis of cesium manganese halide nanocrystals in glass with bright and broad red emission for white LEDs.

ABSTRACT: Recently, lead halide perovskite nanocrystals (NCs) have attracted extensive attention due to their unique optical properties. However, the toxicity of lead and the instability to moisture obstruct their further commercial development. Herein, a series of lead-free CsMnX₃ (X = Cl, Br, and I) NCs embedded in glasses were synthesized by a high temperature solid-state chemistry method. These NCs embedded in glass can remain stable after soaking in water for 90 days. It is found that increasing the amount of cesium carbonate in the synthesis process can not only prevent the oxidation of Mn²⁺ to Mn³⁺ and promote the transparency of glass in the 450-700 nm region, but also significantly increase its photoluminescence quantum yield (PLQY) from 2.9% to 65.1%, which

SUBMITTER: Xu G 

PROVIDER: S-EPMC10207884 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature