Chromium-Based Complexes Bearing Aminophosphine and Phosphine-Imine-Pyrryl Ligands for Selective Ethylene Tri/Tetramerization.

ABSTRACT: A series of Cr-based complexes 6-10 bearing aminophosphine (P,N) ligands Ph₂P-L-NH₂ [L = CH₂CH₂ (1), L = CH₂CH₂CH₂ (2), and L = C₆H₄CH₂ (3)] and phosphine-imine-pyrryl (P,N,N) ligands 2-(Ph₂P-L-N=CH)C₄H₃NH [L = CH₂CH₂CH₂ (4) and L = C₆H₄CH₂ (5)] were prepared, and their catalytic properties were examined for ethylene tri/tetramerization. X-ray crystallographic analysis of complex 8 indicated the κ²-P,N bidentate coordination mode at the Cr(III) center and the distorted octahedral geometry of monomeric P,N-CrCl₃. Up

SUBMITTER: Liu R 

PROVIDER: S-EPMC10210187 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature