Water in the Electrical Double Layer of Ionic Liquids on Graphene.

ABSTRACT: The performance of electrochemical devices using ionic liquids (ILs) as electrolytes can be impaired by water uptake. This work investigates the influence of water on the behavior of hydrophilic and hydrophobic ILs─with ethylsulfate and tris(perfluoroalkyl)trifluorophosphate or bis(trifluoromethyl sulfonyl)imide (TFSI) anions, respectively─on electrified graphene, a promising electrode material. The results show that water uptake slightly reduces the IL electrochemical stability and significantly influences graphene's potential of zero charge, which is justified by the extent of anion depletion from the surface. Experiments confirm the dominant contribution of graphene's quantum capacitance (C_Q) to the total interfacial capacitance (C_int) n

SUBMITTER: Zheng Q 

PROVIDER: S-EPMC10210538 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature