Efficient Spin-Flip between Charge-Transfer States for High-Performance Electroluminescence, without an Intermediate Locally Excited State.

ABSTRACT: Thermally activated delayed fluorescence (TADF) materials with both high photoluminescence quantum yield (PLQY) and fast reverse intersystem crossing (RISC) are strongly desired to realize efficient and stable organic light-emitting diodes (OLEDs). Control of excited-state dynamics via molecular design plays a central role in optimizing the PLQY and RISC rate of TADF materials but remains challenging. Here, 3 TADF emitters possessing similar molecular structures, similar high PLQYs (89.5% to 96.3%), and approximate energy levels of the lowest excited singlet states (S₁), but significantly different spin-flipping RISC rates (0.03 × 10⁶ s^-1 vs. 2.26 × 10⁶ s^-1) and exciton lifetime (297.1 to 332.8 μs vs. 6.0 μs) were systematically synthe

SUBMITTER: Zhang D 

PROVIDER: S-EPMC10214979 | biostudies-literature | 2023

REPOSITORIES: biostudies-literature