Chemical and Electrochemical Reductions of Monoiminoacenaphthenes.

ABSTRACT: Redox properties of monoiminoacenaphthenes (MIANs) were studied using various electrochemical techniques. The potential values obtained were used for calculating the electrochemical gap value and corresponding frontier orbital difference energy. The first-peak-potential reduction of the MIANs was performed. As a result of controlled potential electrolysis, two-electron one-proton addition products were obtained. Additionally, the MIANs were exposed to one-electron chemical reduction by sodium and NaBH₄. Structures of three new sodium complexes, three products of electrochemical reduction, and one product of the reduction by NaBH₄ were studied using single-crystal X-ray diffraction. The MIANs reduced electrochemically by NaBH₄ represent salts, in which the p

SUBMITTER: Khrizanforova VV 

PROVIDER: S-EPMC10218263 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature