Silver Nanocoating of LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Material for Lithium-Ion Batteries.

ABSTRACT: Surface coating has become an effective approach to improve the electrochemical performance of Ni-rich cathode materials. In this study, we investigated the nature of an Ag coating layer and its effect on electrochemical properties of the LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) cathode material, which was synthesized using 3 mol.% of silver nanoparticles by a facile, cost-effective, scalable and convenient method. We conducted structural analyses using X-ray diffraction, Raman spectroscopy, and X-ray photoelectron spectroscopy, which revealed that the Ag nanoparticle coating did not affect the layered structure of NCM811. The Ag-coated sample had less cation mixing compared to the pristine NMC811, which could be attributed to the surface protection of Ag coating from air contamination. The Ag-coated NCM811 exhibited better kinetics than the pristine one, which is attributed to the higher electronic conductivity and better layered structure provided by the Ag nanoparticle coating. The Ag-coated NCM811 delivered a discharge capacity of 185 mAh·g^-1 at the first cycle and 120 mAh·g^-1 at the 100th cycle, respectively, which is better than the pristine NMC811.

SUBMITTER: Li X 

PROVIDER: S-EPMC10221140 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature