Cu@Fe-Redox Capacitive-Based Metal-Organic Framework Film for a High-Performance Supercapacitor Electrode.

ABSTRACT: A metal-organic framework (MOF) is a highly porous material with abundant redox capacitive sites for intercalation/de-intercalation of charges and, hence, is considered promising for electrode materials in supercapacitors. In addition, dopants can introduce defects and alter the electronic structure of the MOF, which can affect its surface reactivity and electrochemical properties. Herein, we report a copper-doped iron-based MOF (Cu@Fe-MOF/NF) thin film obtained via a simple drop-cast route on a 3D-nickel foam (NF) substrate for the supercapacitor application. The as-deposited Cu@Fe-MOF/NF electrodes exhibit a unique micro-sized bipyramidal structure composited with nanoparticles, revealing a high specific capacitance of 420.54 F g^-1 at 3 A g^-1 which is twice compared

SUBMITTER: Patil SA 

PROVIDER: S-EPMC10222974 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature