Nanoscale Thermometry of Plasmonic Structures via Raman Shifts in Copper Phthalocyanine.

ABSTRACT: Temperature measurements at the nanoscale are vital for the application of plasmonic structures in medical photothermal therapy and materials science but very challenging to realize in practice. In this work, we exploit a combination of surface-enhanced Raman spectroscopy together with the characteristic temperature dependence of the Raman peak maxima observed in β-phase copper phthalocyanine (β-CuPc) to measure the surface temperature of plasmonic gold nanoparticles under laser irradiation. We begin by measuring the temperature-dependent Raman shifts of the three most prominent modes of β-CuPc films coated on an array of Au nanodisks over a temperature range of 100-500 K. We then use these calibration curves to determine the temperature of an array of Au nanodisks irradiated with varying

SUBMITTER: Li P 

PROVIDER: S-EPMC10226115 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature