Quantifying Dissolved Transition Metals in Battery Electrolyte Solutions with NMR Paramagnetic Relaxation Enhancement.

ABSTRACT: Transition metal dissolution is an important contributor to capacity fade in lithium-ion cells. NMR relaxation rates are proportional to the concentration of paramagnetic species, making them suitable to quantify dissolved transition metals in battery electrolytes. In this work, ⁷Li, ³¹P, ¹⁹F, and ¹H longitudinal and transverse relaxation rates were measured to study LiPF₆ electrolyte solutions containing Ni²⁺, Mn²⁺, Co²⁺, or Cu²⁺ salts and Mn dissolved from LiMn₂O₄. Sensitivities were found to vary by nuclide and by transition metal. ¹⁹F (PF₆^-) and ¹H (solvent) measurements were more sensitive than ⁷Li and ^31</

SUBMITTER: Allen JP 

PROVIDER: S-EPMC10226131 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature