Nonheme Iron(III) Azide and Iron(III) Isothiocyanate Complexes: Radical Rebound Reactivity, Selectivity, and Catalysis.

ABSTRACT: The new nonheme iron complexes Fe^II(BNPA^Ph2O)(N₃) (1), Fe^III(BNPA^Ph2O)(OH)(N₃) (2), Fe^II(BNPA^Ph2O)(OH) (3), Fe^III(BNPA^Ph2O)(OH)(NCS) (4), Fe^II(BNPA^Ph2O)(NCS) (5), Fe^III(BNPA^Ph2O)(NCS)₂ (6), and Fe^III(BNPA^Ph2O)(N₃)₂ (7) (BNPA^Ph2O = 2-(bis((6-(neopentylamino)pyridin-2-yl) methyl)amino)-1,1-diphenylethanolate) were synthesized and characterized by single crystal X-ray diffraction (XRD), as well as by ¹H NMR, ⁵⁷Fe Mössbauer, and ATR-IR spectroscopies. Complex 2 was reacted with a series of carbon radi

SUBMITTER: Yadav V 

PROVIDER: S-EPMC10226418 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature