Confinement of an alkaline environment for electrocatalytic CO₂ reduction in acidic electrolytes.

ABSTRACT: Acidic electrochemical CO₂ reduction reaction (CO₂RR) can minimize carbonate formation and eliminate CO₂ crossover, thereby improving long-term stability and enhancing single-pass carbon efficiency (SPCE). However, the kinetically favored hydrogen evolution reaction (HER) is generally predominant under acidic conditions. This paper describes the confinement of a local alkaline environment for efficient CO₂RR in a strongly acidic electrolyte through the manipulation of mass transfer processes in well-designed hollow-structured Ag@C electrocatalysts. A high faradaic efficiency of over 95% at a current density of 300 mA cm^-2 and an SPCE of 46.2% at a CO₂ flow rate of 2 standard cubic centimeters per minute are achieved in the a

SUBMITTER: Li X 

PROVIDER: S-EPMC10231308 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature