A nickel-based metal-organic framework as a new cathode for chloride ion batteries with superior cycling stability.

ABSTRACT: Chloride ion batteries (CIBs) have drawn growing attention as attractive candidates for large-scale energy storage technology because of their high theoretical energy densities (2500 W h L^-1), dendrite-free characteristics and abundance of chloride-containing materials available worldwide. However, the further development of CIBs is greatly limited by sluggish Cl^- diffusion and distinct structural variation of cathode materials, resulting in severe decayed capacity and inferior rate performance. Metal-organic framework (MOF) materials possess regular pores/channels and flexible structural designability to accommodate charge carrier ions, but the application of MOFs in anion-type batteries has not been reported. Here, we demonstrate the first example of Ni(dpip) with t

SUBMITTER: Yin Q 

PROVIDER: S-EPMC10231316 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature