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Amphiphilic Janus Particles Confined in Symmetrical and Janus-Like Slits.

ABSTRACT: We use Monte Carlo simulations to investigate the behavior of Janus spheres composed of attractive and repulsive parts confined between two parallel solid surfaces. The slits with identical and competing walls are studied. The adsorption isotherms of Janus particles are determined, and the impact of the density in the pore on the morphology is discussed in detail. So far, this issue has not been systematically investigated. New, unique structures are observed along the isotherms, including the bilayer and three-layer structures located at different distances from the walls. We analyze how selected parameters affect the positional and orientational ordering in these layers. In some cases, the particles form highly ordered hexagonal lattices.

SUBMITTER: Baran L

PROVIDER: S-EPMC10233691 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature

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Amphiphilic Janus Particles Confined in Symmetrical and Janus-Like Slits.

Baran Łukasz Ł Borówko Małgorzata M Rżysko Wojciech W Smołka Jakub J

ACS omega 20230516 21

We use Monte Carlo simulations to investigate the behavior of Janus spheres composed of attractive and repulsive parts confined between two parallel solid surfaces. The slits with identical and competing walls are studied. The adsorption isotherms of Janus particles are determined, and the impact of the density in the pore on the morphology is discussed in detail. So far, this issue has not been systematically investigated. New, unique structures are observed along the isotherms, including the b ...[more]

PMID: 37273616

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Project description:Immobilizing particles on beads, fibers, or filaments, when only one side is exposed to the reaction medium and therefore can be selectively functionalized, is a scalable and easy to control strategy for the fabrication of amphiphilic Janus particles. Here we describe a new, robust method for the fabrication of amphiphilic Janus particles based on immobilization of polymethylsilsesquioxane (PMSQ) particles on polycarbonate (PC), a high impact-resistance polymer with superior mechanical properties. The immobilization of the particles on the PC microspores is performed via inverse solvent displacement method. PMSQ particles are added to a PC solution in tetrahydrofuran (THF), a good solvent for PC. The solution is then precipitated by the introduction of aqueous surfactant solution (antisolvent for PC) under an ultrasonic field. It is important to note that THF and water are miscible and do not form emulsion. During precipitation, PMSQ particles are assembled onto the surface of the PC spherical precipitates/microspheres. The exposed hemispheres of the PMSQ particles are then selectively silanized by (3-Aminopropyl)triethoxysilane (APTES) to introduce amine groups on their surface. To increase the polarity of the functionalized hemispheres, the amine groups are further modified to introduce carboxyl groups. SEM characterization confirms the fine embedment of PMSQ particles onto the PC microspheres. Covalent attachment of silica nanoparticles (NPs) to the functionalized hemispheres of the resulting particles along with fluorescent confocal microscopy conclusively prove the successful fabrication of amphiphilic Janus particles. The immobilization of particles onto highly rigid polymeric microspheres such as PC may pave the way for the development of a robust fabrication procedure with high resistance to temperature fluctuations and harsh mixing conditions that can arise during preparation. This method can be implemented toward a large variety of other synthetic commercial polymers such as polyamide, polyether sulfones, Polyether, ether ketone, or similar.

Dataset Information

Amphiphilic Janus Particles Confined in Symmetrical and Janus-Like Slits.

Publications

Amphiphilic Janus Particles Confined in Symmetrical and Janus-Like Slits.

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