Core-Shell Structured Fluorescent Protein Nanoparticles: New Paradigm Toward Zero-Thermal-Quenching in High-Power Biohybrid Light-Emitting Diodes.

ABSTRACT: Stable and efficient high-power biohybrid light-emitting diodes (Bio-HLEDs) using fluorescent proteins (FPs) in photon downconverting filters have not been achieved yet, reaching best efficiencies of 130 lm W^-1 stable for >5 h. This is related to the rise of the device temperature (70-80 °C) caused by FP-motion and quick heat-transmission in water-based filters, they lead to a strong thermal emission quenching followed by the quick chromophore deactivation via photoinduced H-transfer. To tackle both issues at once, this work shows an elegant concept of a new FP-based nanoparticle, in which the FP core is shielded by a SiO₂ -shell (FP@SiO₂ ) with no loss of the photoluminescence figures-of-merit over years in foreign environments: dry powder at 25 °C (ambien

SUBMITTER: Nieddu M 

PROVIDER: S-EPMC10238177 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature