Doping Engineering of M-N-C Electrocatalyst Based Membrane-Electrode Assembly for High-Performance Aqueous Polysulfides Redox Flow Batteries.

ABSTRACT: Polysulfides aqueous redox flow batteries (PS-ARFBs) with large theoretical capacity and low cost are one of the most promising solutions for large-scale energy storage technology. However, sluggish electrochemical redox kinetics and nonnegligible crossover of aqueous polysulfides restrict the battery performances. Herein, it is found that the Co, Zn dual-doped N-C complex have enhanced electrochemical adsorption behaviors for Na₂ S₂ . It exhibits significantly electrochemical redox activity compared to the bare glassy carbon electrode. And the redox reversibility is also improved from ΔV = 210 mV on Zn-doped N-C complex to ΔV = 164 mV on Co, Zn-doped N-C complex. Furthermore, membrane-electrode assembly (MEA) based on Co, Zn-doped N-C complex is firstly proposed to e

SUBMITTER: Chen B 

PROVIDER: S-EPMC10238193 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature