Mixed Diethanolamine and Polyethyleneimine with Enhanced CO₂ Capture Capacity from Air.

ABSTRACT: Supported polyethyleneimine (PEI) adsorbent is one of the most promising commercial direct air capture (DAC) adsorbents with a long research history since 2002. Although great efforts have been input, there are still limited improvements for this material in its CO₂ capacity and adsorption kinetics under ultradilute conditions. Supported PEI also suffers significantly reduced adsorption capacities when working at sub-ambient temperatures. This study reports that mixing diethanolamine (DEA) into supported PEI can increase 46% and 176% of pseudoequilibrium CO₂ capacities at DAC conditions compared to the supported PEI and DEA, respectively. The mixed DEA/PEI functionalized adsorbents maintain the adsorption capacity at sub-ambient temperatures of -5 to 25 °C. In compari

SUBMITTER: Miao Y 

PROVIDER: S-EPMC10238199 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature