Insights into substitution strategy towards thermodynamic and property regulation of chemically recyclable polymers.

ABSTRACT: The development of chemically recyclable polymers serves as an attractive approach to address the global plastic pollution crisis. Monomer design principle is the key to achieving chemical recycling to monomer. Herein, we provide a systematic investigation to evaluate a range of substitution effects and structure-property relationships in the ɛ-caprolactone (CL) system. Thermodynamic and recyclability studies reveal that the substituent size and position could regulate their ceiling temperatures (T_c). Impressively, M4 equipped with a tert-butyl group displays a T_c of 241 °C. A series of spirocyclic acetal-functionalized CLs prepared by a facile two-step reaction undergo efficient ring-opening polymerization and subsequent depolymerization. The resulting polymers demon

SUBMITTER: Tu YM 

PROVIDER: S-EPMC10238376 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature