Direct observation of coherence transfer and rotational-to-vibrational energy exchange in optically centrifuged CO₂ super-rotors.

ABSTRACT: Optical centrifuges are laser-based molecular traps that can rotationally accelerate molecules to energies rivalling or exceeding molecular bond energies. Here we report time and frequency-resolved ultrafast coherent Raman measurements of optically centrifuged CO₂ at 380 Torr spun to energies beyond its bond dissociation energy of 5.5 eV (J_max = 364, E_rot = 6.14 eV, E_rot/k_B = 71, 200 K). The entire rotational ladder from J = 24 to J = 364 was resolved simultaneously which enabled a more accurate measurement of the centrifugal distortion constants for CO₂. Remarkably, coherence transfer was directly observed, and time-resolved, during the field-free relaxation of the trap as rotational energy flowed into bending-mode vibratio

SUBMITTER: Chen TY 

PROVIDER: S-EPMC10239519 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature