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Crystal structure of 4-[(4-methyl­benz­yl)­oxy]-N′-(4-nitro­benzyl­idene)benzohydrazide: a new hydrazone derivative


ABSTRACT: The title aroylhydrazone ether exists in an E-configuration with respect to the double bond of the hydrazone bridge and with an ac­yl–hydrazone (—CH=N—NH—CO—) torsion angle of 166.0 (3)°. The mol­ecule exhibits a non-planar conformation, likely induced by packing requirements. The mol­ecular structure of the title compound, C22H19N3O4, shows a non-coplanar conformation, with dihedral angles between the phenyl rings of 73.3 (1) and 80.9 (1)°. These deformations are induced by the crystal packing that is mainly governed by N—H⋯O and C—H⋯O hydrogen bonds, forming a mono-periodic arrangement parallel to the b axis.

SUBMITTER: Banna M 

PROVIDER: S-EPMC10242741 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature