Extraction of Se(iv) and Se(vi) from aqueous HCl solution by using a diamide-containing tertiary amine.

ABSTRACT: Here, we investigated the mechanism underlying the extraction of Se(iv) and Se(vi) from aqueous HCl solutions by N-2-ethylhexyl-bis(N-di-2-ethylhexyl-ethylamide)amine (EHBAA). In addition to examining extraction behavior, we also elucidated structural properties of the dominant Se species in solution. Two types of aqueous HCl solutions were prepared by dissolving a Se^IV oxide or a Se^VI salt. X-ray absorption near edge structure analyses revealed that Se(vi) was reduced to Se(iv) in 8 M HCl. Using 0.5 M EHBAA, ∼50% of Se(vi) was extracted from 0.5 M HCl. In contrast, Se(iv) was hardly extracted from 0.5 to 5 M HCl; however, at molar concentrations above 5 M, the extraction efficiency of Se(iv) increased drastically, reaching ∼85%. Slope analyses for the d

SUBMITTER: Narita H 

PROVIDER: S-EPMC10243184 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature