Revealing CO₂ dissociation pathways at vicinal copper (997) interfaces.

ABSTRACT: Size- and shape-tailored copper (Cu) nanocrystals can offer vicinal planes for facile carbon dioxide (CO₂) activation. Despite extensive reactivity benchmarks, a correlation between CO₂ conversion and morphology structure has not yet been established at vicinal Cu interfaces. Herein, ambient pressure scanning tunneling microscopy reveals step-broken Cu nanocluster evolutions on the Cu(997) surface under 1 mbar CO₂(g). The CO₂ dissociation reaction produces carbon monoxide (CO) adsorbate and atomic oxygen (O) at Cu step-edges, inducing complicated restructuring of the Cu atoms to compensate for increased surface chemical potential energy at ambient pressure. The CO molecules bound at under-coordinated Cu atoms contribute to the reversible Cu clust

SUBMITTER: Kim J 

PROVIDER: S-EPMC10244362 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature