Synthesis and structure of two novel trans-platinum complexes.

ABSTRACT: Here for the first time the synthesis and characterization of two new trans-platinum complexes, trans-[PtCl₂{HN=C(OH)C₆H₅}₂] (compound 1) and trans-[PtCl₄(NH₃){HN=C(OH)^tBu}] (compound 2) [with ^tBu = C(CH₃)₃] are described. The structures have been characterized using nuclear magnetic resonance spectroscopy and X-ray single-crystal diffraction. In compound 1 the platinum cation, at the inversion center, is in the expected square-planar coordination geometry. It is coordinated to two chloride anions, trans to each other, and two nitrogen atoms from the benzamide ligands. The van der Waals interactions between the molecules produce extended two-dimensional layers that are linked into

SUBMITTER: Vinci D 

PROVIDER: S-EPMC10245382 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature