Enhanced sub-1 eV detection in organic photodetectors through tuning polymer energetics and microstructure.

ABSTRACT: One of the key challenges facing organic photodiodes (OPDs) is increasing the detection into the infrared region. Organic semiconductor polymers provide a platform for tuning the bandgap and optoelectronic response to go beyond the traditional 1000-nanometer benchmark. In this work, we present a near-infrared (NIR) polymer with absorption up to 1500 nanometers. The polymer-based OPD delivers a high specific detectivity D^* of 1.03 × 10¹⁰ Jones (-2 volts) at 1200 nanometers and a dark current J_d of just 2.3 × 10^-6 ampere per square centimeter at -2 volts. We demonstrate a strong improvement of all OPD metrics in the NIR region compared to previously reported NIR OPD due to the enhanced crystallinity and optimized energy alignment, whi

SUBMITTER: Jacoutot P 

PROVIDER: S-EPMC10246890 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature