NO at low concentration can enhance the formation of highly oxygenated biogenic molecules in the atmosphere.

ABSTRACT: The interaction between nitrogen monoxide (NO) and organic peroxy radicals (RO₂) greatly impacts the formation of highly oxygenated organic molecules (HOM), the key precursors of secondary organic aerosols. It has been thought that HOM production can be significantly suppressed by NO even at low concentrations. Here, we perform dedicated experiments focusing on HOM formation from monoterpenes at low NO concentrations (0 - 82 pptv). We demonstrate that such low NO can enhance HOM production by modulating the RO₂ loss and favoring the formation of alkoxy radicals that can continue to autoxidize through isomerization. These insights suggest that HOM yields from typical boreal forest emissions can vary between 2.5%-6.5%, and HOM formation will not be completely inhibited

SUBMITTER: Nie W 

PROVIDER: S-EPMC10250349 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature