Compressed and Expanded Lattices - Barriers to Spin-State Switching in Mn³⁺ Complexes.

ABSTRACT: We report the structural and magnetic properties of two new Mn³⁺ complex cations in the spin crossover (SCO) [Mn(R-sal₂323)]⁺ series, in lattices with seven different counterions in each case. We investigate the effect on the Mn³⁺ spin state of appending electron-withdrawing and electron-donating groups on the phenolate donors of the ligand. This was achieved by substitution of the ortho and para positions on the phenolate donors with nitro and methoxy substituents in both possible geometric isomeric forms. Using this design paradigm, the [MnL1]⁺ (a) and [MnL2]⁺ (b) complex cations were prepared by complexation of Mn³⁺ to the hexadentate Schiff base ligands with 3-nitro-5-methoxy-phenol

SUBMITTER: Harris MM 

PROVIDER: S-EPMC10251414 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature