Europium(III) Meets Etidronic Acid (HEDP): A Coordination Study Combining Spectroscopic, Spectrometric, and Quantum Chemical Methods.

ABSTRACT: Etidronic acid (1-Hydroxyethylidene-1,1-diphosphonic acid, HEDP, H₄L) is a proposed decorporation agent for U(VI). This paper studied its complex formation with Eu(III), an inactive analog of trivalent actinides, over a wide pH range, at varying metal-to-ligand ratios (M:L) and total concentrations. Combining spectroscopic, spectrometric, and quantum chemical methods, five distinct Eu(III)-HEDP complexes were found, four of which were characterized. The readily soluble EuH₂L⁺ and Eu(H₂L)₂^- species with log β values of 23.7 ± 0.1 and 45.1 ± 0.9 are formed at acidic pH. At near-neutral pH, EuHL⁰_s forms with a log β of ~23.6 and, additionally, a most probably polynuclear complex. The readily dissolved EuL<

SUBMITTER: Heller A 

PROVIDER: S-EPMC10254137 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature