Radiolysis-Assisted Direct Growth of Gold-Based Electrocatalysts for Glycerol Oxidation.

ABSTRACT: The electrocatalytic oxidation of glycerol by metal electrocatalysts is an effective method of low-energy-input hydrogen production in membrane reactors in alkaline conditions. The aim of the present study is to examine the proof of concept for the gamma-radiolysis-assisted direct growth of monometallic gold and bimetallic gold-silver nanostructured particles. We revised the gamma radiolysis procedure to generate free-standing Au and Au-Ag nano- and micro-structured particles onto a gas diffusion electrode by the immersion of the substrate in the reaction mixture. The metal particles were synthesized by radiolysis on a flat carbon paper in the presence of capping agents. We have integrated different methods (SEM, EDX, XPS, XRD, ICP-OES, CV, and EIS) to examine in detail the as-synthesized

SUBMITTER: Tuleushova N 

PROVIDER: S-EPMC10254145 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature