Bis(2,6-pyrazolyl)pyridines as a New Scaffold for Coordination Polymers.

ABSTRACT: Two coordination polymers, Fe(L^OBF₃)(CH₃COO)(CH₃CN)₂]_n•nCH₃CN and [Fe(L^O-)₂AgNO₃BF₄•CH₃OH]_n•1.75nCH₃OH•nH₂O (L^O- = 3,3'-(4-(4-cyanophenyl)pyridine-2,6-diyl)bis(1-(2,6-dichlorophenyl)-1H-pyrazol-5-olate)), were obtained via a PCET-assisted process that uses the hydroxy-pyrazolyl moiety of the ligand and the iron(II) ion as sources of proton and electron, respectively. Our attempts to produce heterometallic compounds under mild conditions of reactant diffusion resulted in the first coordination polymer of 2,6-bis(pyrazol-3-yl)pyridines to retain the core N₃(L)MN₃(L). Under harsh solvothermal condi

SUBMITTER: Nikovskiy IA 

PROVIDER: S-EPMC10254147 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature