Bis(2,6-pyrazolyl)pyridines as a New Scaffold for Coordination Polymers.

ABSTRACT: Two coordination polymers, Fe(L^OBF₃)(CH₃COO)(CH₃CN)₂]_n•nCH₃CN and [Fe(L^O-)₂AgNO₃BF₄•CH₃OH]_n•1.75nCH₃OH•nH₂O (L^O- = 3,3'-(4-(4-cyanophenyl)pyridine-2,6-diyl)bis(1-(2,6-dichlorophenyl)-1H-pyrazol-5-olate)), were obtained via a PCET-assisted process that uses the hydroxy-pyrazolyl moiety of the ligand and the iron(II) ion as sources of proton and electron, respectively. Our attempts to produce heterometallic compounds under mild conditions of reactant diffusion resulted in the first coordination polymer of 2,6-bis(pyrazol-3-yl)pyridines to retain the core N₃(L)MN₃(L). Under harsh solvothermal conditions, a hydrogen atom transfer to the tetrafluoroborate anion caused the transformation of the hydroxyl groups into OBF₃ in the third coordination polymer of 2,6-bis(pyrazol-3-yl)pyridines. This PCET-assisted approach may be applicable to produce coordination polymers and metal-organic frameworks with the SCO-active core N₃(L)MN₃(L) formed by pyrazolone- and other hydroxy-pyridine-based ligands.

SUBMITTER: Nikovskiy IA 

PROVIDER: S-EPMC10254147 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature