A Mechanism Study of Redox Reactions of the Ruthenium-oxo-polypyridyl Complex.
Ontology highlight
ABSTRACT: Over the years, RuIV(bpy)2(py)(O)2+([RuIVO]2+) has garnered considerable interest owing to its extensive use as a polypyridine mono-oxygen complex. However, as the active-site Ru=O bond changes during the oxidation process, [RuIVO]2+ can be used to simulate the reactions of various high-priced metallic oxides. In order to elucidate the hydrogen element transfer process between the Ruthenium-oxo-polypyridyl complex and organic hydride donor, the current study reports on the synthesis of [RuIVO]2+, a polypyridine mono-oxygen complex, in addition to 1H and 3H (organic hydride compounds) and 1H derivative: 2. Through 1H-NMR analysis and thermodynamics- and k
SUBMITTER: Chen BL
PROVIDER: S-EPMC10254183 | biostudies-literature | 2023 May
REPOSITORIES: biostudies-literature
ACCESS DATA
