Construction of the Heterostructure of NiPt Truncated Octahedral Nanoparticle/MoS₂ and Its Interfacial Structure Evolution.

ABSTRACT: Interfacial atomic configuration plays a vital role in the structural stability and functionality of nanocomposites composed of metal nanoparticles (NPs) and two-dimensional semiconductors. In situ transmission electron microscope (TEM) provides a real-time technique to observe the interface structure at atomic resolution. Herein, we loaded bimetallic NiPt truncated octahedral NPs (TONPs) on MoS₂ nanosheets and constructed a NiPt TONPs/MoS₂ heterostructure. The interfacial structure evolution of NiPt TONPs on MoS₂ was in situ investigated using aberration-corrected TEM. It was observed that some NiPt TONPs exhibited lattice matching with MoS₂ and displayed remarkable stability under electron beam irradiation. Intriguingly, the rotation of an individual NiPt TONP can be triggered by the electron beam to match the MoS₂ lattice underneath. Furthermore, the coalescence kinetics of NiPt TONPs can be quantitatively described by the relationship between neck radius (r) and time (t), expressed as rⁿ = Kt. Our work offers a detailed analysis of the lattice alignment relationship of NiPt TONPs on MoS₂, which may enlighten the design and preparation of stable bimetallic metal NPs/MoS₂ heterostructures.

SUBMITTER: Mu C 

PROVIDER: S-EPMC10255085 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature