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The influence of DC voltage on the conductivity of chloroprene rubber-carbon black composites for flexible resistive heating elements.

ABSTRACT: In order to acquire a flexible resistive heating element in the temperature range for human body heating, the influence of DC voltage on chloroprene rubber (CR) and carbon black (CB) composites has been investigated. Three conduction mechanisms have been found to occur in the range from 0.5 V to 10 V - charge velocity increase due to the increase of the electric field, matrix thermal expansion that results in decreased tunnelling currents and new electroconductive channel formation at voltages above 7.5 V, where the temperature exceeds the matrix's softening point. As opposed to external heating, during resistive heating, the composite exhibits a negative temperature coefficient of resistivity up to an applied voltage of 5 V. The intrinsic electro-chemical matrix properties play an important role in the overall resistivity of the composite. The material shows cyclical stability when repeatedly applying a voltage of 5 V and can be used as a human body heating element.

SUBMITTER: Berzina A

PROVIDER: S-EPMC10258886 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature

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The influence of DC voltage on the conductivity of chloroprene rubber-carbon black composites for flexible resistive heating elements.

Berzina Astrida A Klemenoks Igors I Knite Maris M

RSC advances 20230612 26

In order to acquire a flexible resistive heating element in the temperature range for human body heating, the influence of DC voltage on chloroprene rubber (CR) and carbon black (CB) composites has been investigated. Three conduction mechanisms have been found to occur in the range from 0.5 V to 10 V - charge velocity increase due to the increase of the electric field, matrix thermal expansion that results in decreased tunnelling currents and new electroconductive channel formation at voltages a ...[more]

PMID: 37312998

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Project description:Thermal conductivity of natural rubber (NR) was enhanced by incorporating novel conductive hybrid nanofillers, namely polyaniline grafted carbon black (PANI/CB) nanoparticles and carbon black nanoparticles linked with carbon microfiber (CF/CB) composites. The PANI/CB hybrid fillers were synthesized using an in situ method, where aniline monomers were initially adsorbed onto carbon black spherical domains and, afterwards, it was polymerized in the presence of an oxidizer. Final rubber composites were prepared through melt mixing, where PANI/CB and CF/CB filler loading was kept at 40 parts per hundred of rubber (phr). The thermal conductivity values of the rubber composites with CF/CB (20 : 20) and PANI/CB (20 : 20) yield were 0.45 W m-1 K-1 and 0.31 W m-1 K-1, respectively and the thermal conductivity improved significantly compared to the control (0.25 W m-1 K-1) sample. The higher thermal conductivity values of CF/CB and PANI/CB incorporated composites suggest that the generated networked structure of CF and PANI nanofibers with CB nanoparticles has immensely contributed to enhancing the heat dissipation compared to that of the neat CB rubber composite. Scanning electron micrographs (SEM) confirmed the attachment of the synthesized PANI onto the spherical CB nanoparticles and interconnected morphology of CF/CB and PANI/CB hybrid fillers. The synthesized PANI/CB hybrid filler was further characterized using Fourier-transform infrared (FTIR) spectroscopy to evaluate the chemical properties. Furthermore, thermogravimetric analysis revealed the higher thermal stability of CF/CB (20 : 20) and PANI/CB (20 : 20) composites compared to the control. Moreover, the addition of CF/CB (20 : 20) and PANI/CB (20 : 20) improved the mechanical properties such as ultimate tensile strength, modulus at break, resilience and abrasion resistance significantly and well above the minimum required standard mechanical parameters in the tyre industry. These reinforced composites show great potential to be used as heat dissipating rubber composites in the tyre industry.

Dataset Information

The influence of DC voltage on the conductivity of chloroprene rubber-carbon black composites for flexible resistive heating elements.

Publications

The influence of DC voltage on the conductivity of chloroprene rubber-carbon black composites for flexible resistive heating elements.

Similar Datasets

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