Synthesis of N,O-bidentate organic difluoroboron complexes and their photophysical studies.

ABSTRACT: We disclose a novel boron trifluoride induced C-H activation and difluoroboronation at room temperature, thus providing a straightforward gateway to a series of N,O-bidentate organic BF₂ complexes. The scope of the method is demonstrated with 24 examples. All the synthesized compounds exhibit fluorescence and some of them have large Stokes shifts.

SUBMITTER: Guang J 

PROVIDER: S-EPMC10259049 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature