Dataset Information

Strong quenching of dye fluorescence in monomeric perylene orange/TMDC hybrid structures.

ABSTRACT: Hybrid structures with an interface between two different materials with properly aligned energy levels facilitate photo-induced charge separation to be exploited in optoelectronic applications. Particularly, the combination of 2D transition metal dichalcogenides (TMDCs) and dye molecules offers strong light-matter interaction, tailorable band level alignments, and high fluorescence quantum yields. In this work, we aim at the charge or energy transfer-related quenching of the fluorescence of the dye perylene orange (PO) when isolated molecules are brought onto monolayer TMDCs via thermal vapor deposition. Here, micro-photoluminescence spectroscopy revealed a strong intensity drop of the PO fluorescence. For the TMDC emission, in contrast, we observed a relative growth of the trion versus exciton contribution. In addition, fluorescence imaging lifetime microscopy quantified the intensity quenching to a factor of about 10³ and demonstrated a drastic lifetime reduction from 3 ns to values much shorter than the 100 ps width of the instrument response function. From the ratio of the intensity quenching that is attributed to hole or energy transfer from dye to semiconductor, we deduce a time constant of several picoseconds at most, pointing to an efficient charge separation suitable for optoelectronic devices.

SUBMITTER: Volzer T

PROVIDER: S-EPMC10263002 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Strong quenching of dye fluorescence in monomeric perylene orange/TMDC hybrid structures.

Völzer Tim T Schubert Alina A von der Oelsnitz Erik E Schröer Julian J Barke Ingo I Schwartz Rico R Watanabe Kenji K Taniguchi Takashi T Speller Sylvia S Korn Tobias T Lochbrunner Stefan S

Nanoscale advances 20230522 12

Hybrid structures with an interface between two different materials with properly aligned energy levels facilitate photo-induced charge separation to be exploited in optoelectronic applications. Particularly, the combination of 2D transition metal dichalcogenides (TMDCs) and dye molecules offers strong light-matter interaction, tailorable band level alignments, and high fluorescence quantum yields. In this work, we aim at the charge or energy transfer-related quenching of the fluorescence of the ...[more]

PMID: 37325541

Similar Datasets

Project description:Methyl orange (MO) is an organic synthetic dye widely used in laboratory and industrial applications. In laboratory settings, it serves as an acid-base indicator due to its distinct color change in both acidic and alkaline environments. Industrially, it is primarily utilized in the textile industry for its ultraviolet (UV) absorption properties. However, the discharge and leakage of methyl orange into the environment can cause severe ecological damage and pose potential carcinogenic and teratogenic risks to human health. Therefore, detecting and quantifying the concentration of methyl orange in various matrices is crucial. This study reports the synthesis of graphene quantum dots (GQDs) from orange peel as a precursor, using ethanol and dimethylformamide (DMF) as solvents. Cyan (c-GQDs) and yellow (y-GQDs) graphene quantum dots were synthesized through a bottom-up hydrothermal method. The difference in color is attributed to the redshift caused by the varying ratio of pyridine nitrogen to pyrrole nitrogen. These GQDs exhibited notable optical properties, with c-GQDs emitting cyan fluorescence and y-GQDs emitting yellow fluorescence under UV light. To investigate fluorescence quenching effects, nine commonly used dyes were tested, and all were found to quench the fluorescence of y-GQDs, with methyl orange having the most significant effect. The fluorescence quenching of orange peel-derived GQDs in the presence of methyl orange is attributed to poor dispersion in DMF solution. Additionally, the GQDs possess high specific surface area, abundant surface functional groups, and excellent electronic conductivity, which contribute to their effective fluorescence quenching performance. The average thickness of y-GQDs (the vertical dimension from the substrate upwards) was 3.51 nm, confirming their graphene-like structure. They emitted yellow fluorescence within the wavelength range of 450-530 nm. Notably, a significant linear correlation was found between the concentration of methyl orange and the fluorescence intensity of y-GQDs (regression coefficient = 0.9954), indicating the potential of GQDs as effective sensing materials for organic pollutant detection.

Dataset Information

Strong quenching of dye fluorescence in monomeric perylene orange/TMDC hybrid structures.

Publications

Strong quenching of dye fluorescence in monomeric perylene orange/TMDC hybrid structures.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets