Hierarchical structure formation by crystal growth-front instabilities during ice templating.

ABSTRACT: Directional solidification of aqueous solutions and slurries in a temperature gradient is widely used to produce cellular materials through a phase separation of solutes or suspended particles between growing ice lamellae. While this process has analogies to the directional solidification of metallurgical alloys, it forms very different hierarchical structures. The resulting honeycomb-like porosity of freeze-cast materials consists of regularly spaced, lamellar cell walls which frequently exhibit unilateral surface features of morphological complexity reminiscent of living forms, all of which are unknown in metallurgical structures. While the strong anisotropy of ice-crystal growth has been hypothesized to play a role in shaping those structures, the mechanism by which they form has remain

SUBMITTER: Yin K 

PROVIDER: S-EPMC10266019 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature