Three Polyborates with High-Symmetry [B₁₂O₂₄] Units Featuring Different Dimensions of Anion Groups.

ABSTRACT: Three polyborates, namely, LiNa₁₁B₂₈O₄₈, Li_1.45Na_7.55B₂₁O₃₆, and Li₂Na₄Ca₇Sr₂B₁₃O₂₇F₉, were synthesized via the high-temperature solution method. All of them feature high-symmetry [B₁₂O₂₄] units, yet their anion groups exhibit distinct dimensions. LiNa₁₁B₂₈O₄₈ features a three-dimensional anionic structure of ³[B₂₈O₄₈]_∞ framework, which is composed of three units: [B₁₂O₂₄], [B₁₅O₃₀], and [BO₃]. Li_1.45Na_7.55B₂₁O₃₆ possesses a one-dimensional ani

SUBMITTER: Dang Y 

PROVIDER: S-EPMC10268625 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature