Tailored Lewis Acid Sites for High-Temperature Supported Single-Molecule Magnetism.

ABSTRACT: Generating or even retaining slow magnetic relaxation in surface immobilized single-molecule magnets (SMMs) from promising molecular precursors remains a great challenge. Illustrative examples are organolanthanide compounds that show promising SMM properties in molecular systems, though surface immobilization generally diminishes their magnetic performance. Here, we show how tailored Lewis acidic Al(III) sites on a silica surface enable generation of a material with SMM characteristics via chemisorption of (Cp^ttt)₂DyCl ((Cp^ttt)^- = 1,2,4-tri(tert-butyl)-cyclopentadienide). Detailed studies of this system and its diamagnetic Y analogue indicate that the interaction of the metal chloride with surface Al sites results in a change of the coordi

SUBMITTER: Bernhardt M 

PROVIDER: S-EPMC10273314 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature