Enabling long-cycling aqueous sodium-ion batteries via Mn dissolution inhibition using sodium ferrocyanide electrolyte additive.

ABSTRACT: Aqueous sodium-ion batteries (AIBs) are promising candidates for large-scale energy storage due to their safe operational properties and low cost. However, AIBs have low specific energy (i.e., <80 Wh kg^-1) and limited lifespans (e.g., hundreds of cycles). Mn-Fe Prussian blue analogues are considered ideal positive electrode materials for AIBs, but they show rapid capacity decay due to Jahn-Teller distortions. To circumvent these issues, here, we propose a cation-trapping method that involves the introduction of sodium ferrocyanide (Na₄Fe(CN)₆) as a supporting salt in a highly concentrated NaClO₄-based aqueous electrolyte solution to fill the surface Mn vacancies formed in Fe-substituted Prussian blue Na_1.58Fe_0.07Mn_0.97<

SUBMITTER: Liang Z 

PROVIDER: S-EPMC10275921 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature