The role of ion solvation in lithium mediated nitrogen reduction.

ABSTRACT: Since its verification in 2019, there have been numerous high-profile papers reporting improved efficiency of lithium-mediated electrochemical nitrogen reduction to make ammonia. However, the literature lacks any coherent investigation systematically linking bulk electrolyte properties to electrochemical performance and Solid Electrolyte Interphase (SEI) properties. In this study, we discover that the salt concentration has a remarkable effect on electrolyte stability: at concentrations of 0.6 M LiClO₄ and above the electrode potential is stable for at least 12 hours at an applied current density of -2 mA cm^-2 at ambient temperature and pressure. Conversely, at the lower concentrations explored in prior studies, the potential required to maintain a given N₂

SUBMITTER: Westhead O 

PROVIDER: S-EPMC10281334 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature