Electrochemical conversion of CO₂ using metal-organic framework catalysts.

ABSTRACT: Metal-organic frameworks (MOFs) have been an excellent platform for carbon dioxide reduction reactions (CO₂RR). In this work, the feasibility of electrochemical reduction of CO₂ to obtain C₂-deep value-added products was investigated by the preparation of Mg-containing MOF-74 samples combined with transition metal cations (Ni²⁺, Co²⁺ and Zn²⁺). The prepared MOFs were used as electrocatalysts in CO₂RR. Chronoamperometric analysis coupled to ATR-FTIR spectroscopy was employed to characterize the CO₂ reduction products and subsequently via ¹H NMR. Although an isostructural crystalline structure was observed in all synthesized MOFs, the pore diameter distribution was significantly affected due to

SUBMITTER: Espinosa-Flores RA 

PROVIDER: S-EPMC10285178 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature