Direct gas-phase formation of formic acid through reaction of Criegee intermediates with formaldehyde.

ABSTRACT: Ozonolysis of isoprene is considered to be an important source of formic acid (HCOOH), but its underlying reaction mechanisms related to HCOOH formation are poorly understood. Here, we report the kinetic and product studies of the reaction between the simplest Criegee intermediate (CH₂OO) and formaldehyde (HCHO), both of which are the primary products formed in ozonolysis of isoprene. By utilizing time-resolved infrared laser spectrometry with the multifunctional dual-comb spectrometers, the rate coefficient k_CH2OO+HCHO is determined to be (4.11 ± 0.25) × 10^-12 cm³ molecule^-1 s^-1 at 296 K and a negative temperature dependence of the rate coefficient is observed and described by an Arrhenius expression with an activation ener

SUBMITTER: Luo PL 

PROVIDER: S-EPMC10287650 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature