Thermally-assisted photosensitized emission in a trivalent terbium complex.

ABSTRACT: Luminescent lanthanide complexes containing effective photosensitizers are promising materials for use in displays and sensors. The photosensitizer design strategy has been studied for developing the lanthanide-based luminophores. Herein, we demonstrate a photosensitizer design using dinuclear luminescent lanthanide complex, which exhibits thermally-assisted photosensitized emission. The lanthanide complex comprised Tb(III) ions, six tetramethylheptanedionates, and phosphine oxide bridge containing a phenanthrene frameworks. The phenanthrene ligand and Tb(III) ions are the energy donor (photosensitizer) and acceptor (emission center) parts, respectively. The energy-donating level of the ligand (lowest excited triplet (T₁) level = 19,850 cm^-1) is lower than the emittin

SUBMITTER: Kitagawa Y 

PROVIDER: S-EPMC10287744 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature