In-situ preparation of sulfonated carbonaceous copper oxide-zirconia nanocomposite as a novel and recyclable solid acid catalyst for reduction of 4-nitrophenol.

ABSTRACT: The missing-linker defects of UiO-66 were exploited to covalently anchor Cu nanoclusters (Cu/UiO-66). The molecular interactions between the metals and oxides as copper-zirconia interfaces in Cu/UiO-66 are essential for heterogeneous catalysis, leading to remarkable synergistic impacts on activity and selectivity. Homogeneously distributed carbonaceous mixed metal oxides (CuO/ZrO₂@C) nanocomposite was prepared via carbonization of the Cu/UiO-66 at 600 °C for 3 h in air. To enhance the acidity properties of the CuO/ZrO₂@C nanocomposite, a small amount of sulfuric acid was added and heated at 150 °C under an N₂ atmosphere (CuO/ZrO₂-SO₃H@C). The synthesised Cu/UiO-66 and CuO/ZrO₂-SO₃H@C catalysts were used as novel c

SUBMITTER: Farrag M 

PROVIDER: S-EPMC10287755 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature