Colloid driven low supersaturation crystallization for atomically thin Bismuth halide perovskite.

ABSTRACT: It is challenging to grow atomically thin non-van der Waals perovskite due to the strong electronic coupling between adjacent layers. Here, we present a colloid-driven low supersaturation crystallization strategy to grow atomically thin Cs₃Bi₂Br₉. The colloid solution drives low-concentration solute in a supersaturation state, contributing to initial heterogeneous nucleation. Simultaneously, the colloids provide a stable precursor source in the low-concentration solute. The surfactant is absorbed in specific crystal nucleation facet resulting in the anisotropic growth of planar dominance. Ionic perovskite Cs₃Bi₂Br₉ is readily grown from monolayered to six-layered Cs₃Bi₂Br₉ corresponding to th

SUBMITTER: Li L 

PROVIDER: S-EPMC10290062 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature