Halide-assisted differential growth of chiral nanoparticles with threefold rotational symmetry.

ABSTRACT: Enriching the library of chiral plasmonic nanoparticles that can be chemically mass-produced will greatly facilitate the applications of chiral plasmonics in areas ranging from constructing optical metamaterials to sensing chiral molecules and activating immune cells. Here we report on a halide-assisted differential growth strategy that can direct the anisotropic growth of chiral Au nanoparticles with tunable sizes and diverse morphologies. Anisotropic Au nanodisks are employed as seeds to yield triskelion-shaped chiral nanoparticles with threefold rotational symmetry and high dissymmetry factors. The averaged scattering g-factors of the L- and D-nanotriskelions are as large as 0.57 and - 0.49 at 650 nm, respectively. The Au nanotriskelions have been applied in chiral optical switching dev

SUBMITTER: Zheng J 

PROVIDER: S-EPMC10290678 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature