Asymmetric dinitrogen-coordinated nickel single-atomic sites for efficient CO₂ electroreduction.

ABSTRACT: Developing highly efficient, selective and low-overpotential electrocatalysts for carbon dioxide (CO₂) reduction is crucial. This study reports an efficient Ni single-atom catalyst coordinated with pyrrolic nitrogen and pyridinic nitrogen for CO₂ reduction to carbon monoxide (CO). In flow cell experiments, the catalyst achieves a CO partial current density of 20.1 mA cm_geo^-2 at -0.15 V vs. reversible hydrogen electrode (V_RHE). It exhibits a high turnover frequency of over 274,000 site^-1 h^-1 at -1.0 V_RHE and maintains high Faradaic efficiency of CO (FE_CO) exceeding 90% within -0.15 to -0.9 V_RHE. Operando synchrotron-based infrared and X-ray absorption spectra, and theoretical calcul

SUBMITTER: Zhou Y 

PROVIDER: S-EPMC10290683 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature