Directed Assembly of Au Nanostar@Ag Satellite Nanostructures for SERS-Based Sensing of Hg²⁺ Ions.

ABSTRACT: Embedding Raman reporters within nanosized gaps of metallic nanoparticles is an attractive route for surface-enhanced Raman spectroscopy (SERS) applications, although often this involves complex synthesis procedures that limit their practical use. Herein, we present the tip-selective direct growth of silver satellites surrounding gold nanostars (AuNSt@AgSAT), mediated by a dithiol Raman reporter 1,4-benzenedithiol (BDT). We propose that BDT is embedded within nanogaps which form between the AuNSt tips and the satellites, and plays a key role in mediating the satellite growth. Not only proposing a rationale for the mechanistic growth of the AuNSt@AgSAT, we also demonstrate an example for its use for the detection of Hg²⁺ ions in water. The presence of Hg²⁺ resulted in

SUBMITTER: Ellis MG 

PROVIDER: S-EPMC10294701 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature