Superior cyclability of high surface area vanadium nitride in salt electrolytes.

ABSTRACT: High surface area vanadium nitrides (VNs) have been extensively studied as materials for aqueous supercapacitors due to the high initial capacitance in alkaline media at low scan rates. However, low capacitance retention and safety limit their implementation. The use of neutral aqueous salt solutions has the potential to mitigate both of these concerns, but is limited in analysis. Hence, we report on the synthesis and characterization of high surface area VN as a supercapacitor material in a wide variety of aqueous chlorides and sulfates using Mg²⁺, Ca²⁺, Na⁺, K⁺, and Li⁺ ions. We observe the following trend in the salt electrolytes: Mg²⁺ > Li⁺ > K⁺ > Na⁺ > Ca²⁺. Mg²⁺ sy

SUBMITTER: Kasten J 

PROVIDER: S-EPMC10295220 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature