Selective C-H Bond Cleavage with a High-Spin Fe^IV-Oxido Complex.

ABSTRACT: Non-heme Fe monooxygenases activate C-H bonds using intermediates with high-spin Fe^IV-oxido centers. To mimic these sites, a new tripodal ligand [pop]^3- was prepared that contains three phosphoryl amido groups that are capable of stabilizing metal centers in high oxidation states. The ligand was used to generate [Fe^IVpop(O)]^-, a new Fe^IV-oxido complex with an S = 2 spin ground state. Spectroscopic measurements, which included low-temperature absorption and electron paramagnetic resonance spectroscopy, supported the assignment of a high-spin Fe^IV center. The complex showed reactivity with benzyl alcohol as the external substrate but not with related compounds (e.g., ethyl benzene and benzyl methyl ether), suggesting th

SUBMITTER: Sun C 

PROVIDER: S-EPMC10301140 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature