New Network Polymer Electrolytes Based on Ionic Liquid and SiO₂ Nanoparticles for Energy Storage Systems.

ABSTRACT: Elementary processes of electro mass transfer in the nanocomposite polymer electrolyte system by pulse field gradient, spin echo NMR spectroscopy and the high-resolution NMR method together with electrochemical impedance spectroscopy are examined. The new nanocomposite polymer gel electrolytes consisted of polyethylene glycol diacrylate (PEGDA), salt LiBF₄ and 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF₄) and SiO₂ nanoparticles. Kinetics of the PEGDA matrix formation was studied by isothermal calorimetry. The flexible polymer-ionic liquid films were studied by IRFT spectroscopy, differential scanning calorimetry and temperature gravimetric analysis. The total conductivity in these systems was about 10^-4 S cm^-1 (-40 °C), 10

SUBMITTER: Khatmullina KG 

PROVIDER: S-EPMC10301224 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature